Error in Visual Studio while loading image from OpenCV

I was trying to load an Image in Visual Studio 2013 (on 32-bit Windows machine), using OpenCV 2.4.10, but came across an error as: "Unable to start program 'C:\\Documents\Visual Studio 2013\Projects\FirstOpenCV\x64\Debug\FirstOpenCV.exe'

Is there anyway by which I can place the Screenshot of the error page?